Effect of catalyst deposition on electrode structure, mass transport and performance of polymer electrolyte membrane fuel cells

Jian Zhao, Samaneh Shahgaldi, Adnan Ozden, Ibrahim E. Alaefour, Xianguo Li and Feridun Hamdullahpur

Applied Energy, 2019, vol. 255, issue C

Abstract: Electrode structure determines the rate of transport and electrochemical reactions and is significantly affected by the catalyst deposition method. In this study, the effect of catalyst deposition is investigated on the pore structure, mass transport, and operating performance of the catalyzed electrodes prepared by the methods of catalyst coated on membrane (CCM) and catalyst coated on substrate (CCS). The result indicates that the CCS electrode is thinner, yielding larger porosity, smaller geometric pore surface area, smaller diffusion and permeation resistivity, and lower cell performance. The maximum power density of the CCS electrodes is only about 4% smaller than that of the CCM electrodes at high Pt loadings (0.4 mg·cm−2), while it is as much as 60% less than that of the CCM counterparts at low Pt loadings (0.1 mg·cm−2). The significant performance drop for the low-Pt-loading CCS electrodes is due to the relatively low surface area in the catalyst layers resulted from catalyst penetration into the pores of the gas diffusion layer, even though the mass transfer resistivity is smaller than their CCM counterparts. The CCS method is therefore unsuitable for low-Pt-loading electrodes (<0.1 mg·cm−2) unless the material penetration and the resulting performance deterioration can be inhibited.

Keywords: Catalyst layer; Pore structure; Diffusion resistivity; Permeation resistivity; Polarization curve (search for similar items in EconPapers)
Date: 2019
References: Add references at CitEc
Citations: View citations in EconPapers (2)

Downloads: (external link)
http://www.sciencedirect.com/science/article/pii/S0306261919314898
Full text for ScienceDirect subscribers only

Related works:
This item may be available elsewhere in EconPapers: Search for items with the same title.

Export reference: BibTeX RIS (EndNote, ProCite, RefMan) HTML/Text

Persistent link: https://EconPapers.repec.org/RePEc:eee:appene:v:255:y:2019:i:c:s0306261919314898

Ordering information: This journal article can be ordered from
http://www.elsevier.com/wps/find/journaldescription.cws_home/405891/bibliographic
http://www.elsevier. ... 405891/bibliographic

DOI: 10.1016/j.apenergy.2019.113802

Access Statistics for this article

Applied Energy is currently edited by J. Yan

More articles in Applied Energy from Elsevier
Bibliographic data for series maintained by Catherine Liu ().