Experimental research on self-preservation effect of methane hydrate in porous sediments

Yan Xie, Tao Zheng, Jin-Rong Zhong, Yu-Jie Zhu, Yun-Fei Wang, Yu Zhang, Rui Li, Qing Yuan, Chang-Yu Sun and Guang-Jin Chen

Applied Energy, 2020, vol. 268, issue C, No S0306261920305201

Abstract: The self-preservation is considered as an advantageous property for natural gas hydrate transportation and storage. However, it may also bring serious troubles for well drilling and hydrate exploitation. In this work, various factors affecting the self-preservation effect of CH4 hydrate were investigated by using HP μ-DSC. The results indicate the presence of porous sediments does not influence the anomalous self-preservation region of CH4 hydrate. The CH4 hydrate dissociation rate increases with the decreased initial water content and quartz sand particle size as a whole. However, the self-preservation could be still found in a very low initial water content (10 vol%) and small-particle sediments (25–38 μm) condition. On the other hand, an enhanced self-preservation effect and excessive pressure phenomenon were unexpectedly found in bentonite and kaolin. The hydrate can still maintain high metastability with hardly any decomposition after the pressure was released to atmospheric pressure. In situ Raman and CCD camera were used for the further study of the mechanism. We speculate the interaction of hydrogen bonds between bentonite and hydrate might be the main reason for this abnormal phenomenon. The knowledge gained in this work is significant for the comprehension of CH4 hydrate dissociation in porous sediments below ice point, and provides a better understanding of the self-preservation mechanism.

Keywords: Self-preservation; CH4 hydrate; Bentonite; Enhanced self-preservation; Particle size (search for similar items in EconPapers)
Date: 2020
References: View references in EconPapers View complete reference list from CitEc
Citations: View citations in EconPapers (11)

Downloads: (external link)
http://www.sciencedirect.com/science/article/pii/S0306261920305201
Full text for ScienceDirect subscribers only

Related works:
This item may be available elsewhere in EconPapers: Search for items with the same title.

Export reference: BibTeX RIS (EndNote, ProCite, RefMan) HTML/Text

Persistent link: https://EconPapers.repec.org/RePEc:eee:appene:v:268:y:2020:i:c:s0306261920305201

Ordering information: This journal article can be ordered from
http://www.elsevier.com/wps/find/journaldescription.cws_home/405891/bibliographic
http://www.elsevier. ... 405891/bibliographic

DOI: 10.1016/j.apenergy.2020.115008

Access Statistics for this article

Applied Energy is currently edited by J. Yan

More articles in Applied Energy from Elsevier
Bibliographic data for series maintained by Catherine Liu ().