Parameter analysis from the modeling of high temperature proton exchange membrane fuel cells

Eunji Kim, Seunghwan Song, Seoeun Choi, Jung Ock Park, Junghwan Kim and Kyungjung Kwon

Applied Energy, 2021, vol. 301, issue C, No S0306261921008758

Abstract: High temperature proton exchange membrane fuel cells (PEMFCs) employing phosphoric acid (PA)-doped polymer membranes could be an alternative capable of overcoming the disadvantages of low temperature PEMFCs. Four critical membrane-electrode assembly (MEA) parameters (cathode exchange current density, cathode utilization, ohmic resistance, and cathode limiting current density) are selected and extracted from the modeling of twenty-two polarization curves measured from nineteen MEAs, which are fabricated and operated according to an experimental protocol that Samsung developed in the mid 2000s. MEA systems adopting three representative membranes (polybenzimidazole (PBI), poly(2,5-benzimidazole) (ABPBI), polybenzoxazine (PBOA)) are compared, and the effect of monomer ratio in two representative benzoxazine-benzimidazole copolymer membranes is analyzed. The evolution of the parameters during the break-in period of MEAs and the period of 2008 to 2018, when MEA performance was improved with the same specification of catalysts and membrane, is examined. Also, the impact of PA impregnation in the cathode is investigated when PA is additionally impregnated in the cathode in addition to a PA-doped membrane. Optimum values of the four parameters are combined to simulate the highest MEA performance, and the MEA performance is predicted in some cases where the parameters are varied. Overall, this approach expands the scope of previous literature on the modeling of high temperature PEMFCs, which have been mostly based on PBI membrane systems, by introducing new parameters such as the catalyst utilization and by applying the model to various membrane systems and phenomena.

Keywords: Proton exchange membrane fuel cell; Membrane-electrode assembly; Phosphoric acid; Modeling; High temperature; Polybenzimidazole (search for similar items in EconPapers)
Date: 2021
References: View references in EconPapers View complete reference list from CitEc
Citations: View citations in EconPapers (1)

Downloads: (external link)
http://www.sciencedirect.com/science/article/pii/S0306261921008758
Full text for ScienceDirect subscribers only

Related works:
This item may be available elsewhere in EconPapers: Search for items with the same title.

Export reference: BibTeX RIS (EndNote, ProCite, RefMan) HTML/Text

Persistent link: https://EconPapers.repec.org/RePEc:eee:appene:v:301:y:2021:i:c:s0306261921008758

Ordering information: This journal article can be ordered from
http://www.elsevier.com/wps/find/journaldescription.cws_home/405891/bibliographic
http://www.elsevier. ... 405891/bibliographic

DOI: 10.1016/j.apenergy.2021.117488

Access Statistics for this article

Applied Energy is currently edited by J. Yan

More articles in Applied Energy from Elsevier
Bibliographic data for series maintained by Catherine Liu ().