Visible light-driven dual photoelectrode microbial electrosynthesis using BiVO4-RuO2-IrO2 on Ti mesh photoanode and ZIF-67/g-C3N4 on carbon felt photocathode for the efficient reduction of CO2 into acetate

Tao Li, Yu Chen, Kang Zhang, Xiangling Li, Tianshun Song and Jingjing Xie

Applied Energy, 2023, vol. 348, issue C, No S030626192300973X

Abstract: Microbial electrosynthesis (MES) systems integrated with solar energy (photoelectrode-assisted MES) represent an attractive method for the fixation of CO2 through microbial electrochemical processes. In this study, BiVO4-RuO2-IrO2/Ti with long-term stability and corrosion resistance was used as photoanode through the electrophoretic deposition of BiVO4 on RuO2-IrO2/Ti mesh, significantly reducing the charge recombination rate and enhancing the oxygen evolution reaction (OER) ability. Simultaneously, the ZIF-67/g-C3N4 photocathode can significantly increase CO2 absorption and hydrogen production by enhancing electron–hole separation ability under visible light. Consequently, the MES system with the BiVO4-RuO2-IrO2/Ti anode and ZIF-67/g-C3N4 photocathode obtained an acetate yield of 0.46 g/L/d at −0.9 V versus Ag/AgCl within 14 days. This value was 4.6 times that under dark conditions. The solar-to-acetate conversion efficiency was determined to be 1.52%. Furthermore, the MES with dual photoelectrode still obtained an acetate yield of 0.09 g/L/d at −0.6 V versus Ag/AgCl. These results showed that the MES with the BiVO4-RuO2-IrO2/Ti photoanode and ZIF-67/g-C3N4 photocathode reduced OER overpotential, increased electron transport rate, and improved CO2 supply for the simultaneous supplementation of substrates and electrons in MES. This work provides a new strategy for constructing efficient photoelectrodes in MES to achieve highly efficient chemical generation for CO2 transformation under solar light.

Keywords: Microbial electrosynthesis; Acetate; BiVO4-RuO2-IrO2/Ti; ZIF-67/g-C3N4; Photoelectrode (search for similar items in EconPapers)
Date: 2023
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DOI: 10.1016/j.apenergy.2023.121609

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