Effect of fast charging on degradation and safety characteristics of lithium-ion batteries with LiFePO4 cathodes

Hanwei Zhou, Anuththara S. Alujjage, Maria Terese, Conner Fear, Tapesh Joshi, Vallabha Rao Rikka, Judith A. Jeevarajan and Partha P. Mukherjee

Applied Energy, 2025, vol. 377, issue PA, No S0306261924018488

Abstract: Fast charging compatibility is a desirable feature for batteries to shape a promising future in our rechargeable world. Enabling fast charging of advanced energy-dense Li-ion batteries for growing electric vehicle (EV) markets depends on the breakthrough of material chemistry and optimization of charging strategy. Lithium iron phosphate (LiFePO4, or LFP) is a pivotal cathode material in state-of-the-art EV batteries due to the merits of high thermal stability, long cycle lifetime, and high-temperature performance. However, degradation-safety interactions of LFP-based Li-ion batteries under fast charging conditions and low temperatures remain elusive. In this study, we cycle LFP cells under different fast charging strategies and thermal environments to understand their effects on degradation pathways, where the capacity, voltage, temperature, coulombic inefficiency, internal resistance, and impedance spectroscopy are evaluated. Half-cell studies are implemented to assess electrode-level capacity retentions. Post-mortem analyses are conducted to reveal physicochemical changes in electrodes. Accelerating rate calorimeter tests are carried out to measure evolutions of cell-level thermal instabilities after fast charging tests. This research article highlights the significant roles of graphite-centric lithium plating and LFP-centric transition metal dissolution in driving substantial electrochemical degradations, suggesting that a mild low temperature does not necessarily reduce the LFP cell lifetime.

Keywords: Lithium-ion battery; Fast charging; LFP cathode; Degradation mechanism; Accelerating Rate Calorimeter; Thermal Stability; Battery Safety (search for similar items in EconPapers)
Date: 2025
References: View references in EconPapers View complete reference list from CitEc
Citations:

Downloads: (external link)
http://www.sciencedirect.com/science/article/pii/S0306261924018488
Full text for ScienceDirect subscribers only

Related works:
This item may be available elsewhere in EconPapers: Search for items with the same title.

Export reference: BibTeX RIS (EndNote, ProCite, RefMan) HTML/Text

Persistent link: https://EconPapers.repec.org/RePEc:eee:appene:v:377:y:2025:i:pa:s0306261924018488

Ordering information: This journal article can be ordered from
http://www.elsevier.com/wps/find/journaldescription.cws_home/405891/bibliographic
http://www.elsevier. ... 405891/bibliographic

DOI: 10.1016/j.apenergy.2024.124465

Access Statistics for this article

Applied Energy is currently edited by J. Yan

More articles in Applied Energy from Elsevier
Bibliographic data for series maintained by Catherine Liu ().