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NixCo1-x(OH)2 nanosheets on carbon nanofoam paper as high areal capacity electrodes for hybrid supercapacitors

Tuyen Nguyen, Michel Boudard, M. João Carmezim and M. Fátima Montemor

Energy, 2017, vol. 126, issue C, 208-216

Abstract: This work reports the charge storage ability of NixCo1-x(OH)2 nanosheet-carbon nanofoam paper (CNFP) composites prepared by electrodeposition for high areal capacity supercapacitor electrodes. The NixCo1-x(OH)2 film grew through instantaneous nucleation, uniformly covered CNFP, and displayed a porous morphology composed of a nanosheet percolation network. The electrochemical response of the NixCo1-x(OH)2 films was tuned by varying the Co to Ni ratios. The optimized NixCo1-x(OH)2 stoichiometry resulted in Ni0.33Co0.67(OH)2-CNFP electrodes displaying areal capacity/capacitance values of 1.52 C cm−2/2.03 F cm−2 at 2.1 mA cm−2, resulting from the contribution of the double layer capacity of CNFP with the redox capacity of NixCo1-x(OH)2. A two electrode cell composed of CNFP as negative electrode and NixCo1-x(OH)2-CNFP as positive electrode presented a high areal capacity value of 0.73 C cm−2 at 7.2 mA cm−2.

Keywords: Supercapacitors; NixCo1-x(OH)2; Hydroxides; Nanosheets; Carbon nanofoams; Energy storage (search for similar items in EconPapers)
Date: 2017
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Citations: View citations in EconPapers (3)

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Persistent link: https://EconPapers.repec.org/RePEc:eee:energy:v:126:y:2017:i:c:p:208-216

DOI: 10.1016/j.energy.2017.03.024

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