An experimental study of a thermochemical regeneration waste heat recovery process using a reformer unit

Christian Gaber, Martin Demuth, René Prieler, Christoph Schluckner and Christoph Hochenauer

Energy, 2018, vol. 155, issue C, 381-391

Abstract: This paper presents a thermochemical regenerative heat recovery process for utilizing the waste heat of oxy-fuel furnaces, with three significant modifications compared to current state-of-the-art reforming concepts. (I) Experimental tests with a reformer test rig were performed, in order to investigate the bi-reforming of methane into syngas by using water and carbon dioxide with a steam-to-carbon ratio of 0.5. The measured syngas concentrations were compared to calculated equilibrium values and carbon deposits were determined. A methane conversion rate of 95.3% was achieved. (II) Carbon deposits in a regenerator bed are usually burned with purge gases. In contrast to this procedure, oxygen was added to the fuel/exhaust gas mixture in order to cause tri-reforming of methane with a steam-to-carbon ratio of 0.4. The syngas concentrations were compared to equilibrium values and it was found, that tri-reforming significantly reduces carbon formation. A methane conversion rate of 96.7% was achieved. (III) Furthermore, reforming and regeneration cycles were coupled and it was found that the temperature profile within the TCR regenerator bed material varies greatly from that of a common regenerator. Regeneration with water and carbon dioxide was sufficient to eliminate all carbon deposits.

Keywords: Waste heat recovery; Oxy-fuel furnace; Thermochemical regeneration; Syngas; Bi- and tri-reforming of methane; Carbon formation (search for similar items in EconPapers)
Date: 2018
References: View references in EconPapers View complete reference list from CitEc
Citations: View citations in EconPapers (15)

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Persistent link: https://EconPapers.repec.org/RePEc:eee:energy:v:155:y:2018:i:c:p:381-391

DOI: 10.1016/j.energy.2018.04.154

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