Morphology-controlled synthesis of microencapsulated phase change materials with TiO2 shell for thermal energy harvesting and temperature regulation

Huan Liu, Xiaodong Wang, Dezhen Wu and Shengfu Ji

Energy, 2019, vol. 172, issue C, 599-617

Abstract: In this work, we designed and fabricated three types of n-eicosane/TiO2-based microcapsules with different morphologies through an emulsion-templated interfacial polycondensation route, followed by the structure-inducing formation of TiO2 shell. As we expected, the resultant microcapsules achieved the tubular, octahedral and spherical morphologies as well as a well-defined core-shell microstructure under the structure-directing control with different crystallization promoters. X-ray diffraction confirmed that the tubular microcapsules obtained a crystalline TiO2 (B) shell, whereas a brookite TiO2 shell was formed for the octahedral and spherical microcapsules. According to the thermal analysis under the isothermal and nonisothermal conditions, the tubular microcapsules showed the fastest thermal response due to their specific internal nanostructures, and the spherical microcapsules presented the largest amounts of charged and discharged heat because of their highest effective encapsulation ratio of n-eicosane core. These three types of microcapsules achieved a good energy storage capability in an order of the spherical microcapsules > the octahedral microcapsules > the tubular microcapsules, and all of them presented a diverse range of superior performance including excellent temperature-regulating and photocatalytic capabilities, good thermal reliability and durability, good shape stability and prominent heat charging/discharging performance when used for thermal energy harvesting and temperature regulation.

Keywords: Phase change materials; TiO2 shell; Morphology control; Thermal energy harvesting; Temperature regulation; Photocatalytic activity (search for similar items in EconPapers)
Date: 2019
References: View references in EconPapers View complete reference list from CitEc
Citations: View citations in EconPapers (9)

Downloads: (external link)
http://www.sciencedirect.com/science/article/pii/S0360544219301677
Full text for ScienceDirect subscribers only

Related works:
This item may be available elsewhere in EconPapers: Search for items with the same title.

Export reference: BibTeX RIS (EndNote, ProCite, RefMan) HTML/Text

Persistent link: https://EconPapers.repec.org/RePEc:eee:energy:v:172:y:2019:i:c:p:599-617

DOI: 10.1016/j.energy.2019.01.151

Access Statistics for this article

Energy is currently edited by Henrik Lund and Mark J. Kaiser

More articles in Energy from Elsevier
Bibliographic data for series maintained by Catherine Liu ().