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Structural properties and supercapacitive performance evaluation of the nickel oxide/graphene/polypyrrole hybrid ternary nanocomposite in aqueous and organic electrolytes

Sanaz Zarabi Golkhatmi, Arman Sedghi, Hoda Nourmohammadi Miankushki and Maryam Khalaj

Energy, 2021, vol. 214, issue C

Abstract: Recently, hybrid supercapacitors have attracted tremendous attention as promising energy storage and conversion devices due to their excellent energy density and high power density. In the present work, a novel pioneering hybrid ternary nanocomposite of NiO/Gr/PPy was synthesized by a low-cost co-precipitation method, followed by heat treatment and in-situ chemical polymerization. The as-synthesized nanocomposite was drop-cast on a modified Cu current collector to enhance the supercapacitive performance and stability in the electrolyte. The results of electrochemical characterization in 6 M KOH revealed the high specific capacitance and energy density of 970.85 F g−1 and 33.71 Wh kg−1 at 1 A g−1, respectively. This can be attributed to the synergic effect and hybrid performance of NiO, Gr, and PPy. Moreover, a full symmetric cell was assembled by using this hybrid ternary nanocomposite and evaluated in TEA-BF4/AN. The results showed the high specific capacitance and energy density of 66.17 F g−1 and 36.76 Wh kg−1 within the 2 V potential window, respectively.

Keywords: Supercapacitor; Hybrid ternary nanocomposite; Current collector; Nickel oxide (NiO); Graphene (Gr); Polypyrrole (PPy) (search for similar items in EconPapers)
Date: 2021
References: View references in EconPapers View complete reference list from CitEc
Citations: View citations in EconPapers (3)

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Persistent link: https://EconPapers.repec.org/RePEc:eee:energy:v:214:y:2021:i:c:s0360544220320570

DOI: 10.1016/j.energy.2020.118950

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