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The production of Zn from ZnO in a two-step solar process utilizing FeO and Fe3O4

J. Millar, R.D. Palumbo, A. Rouanet and G. Pichelin

Energy, 1997, vol. 22, issue 2, 301-309

Abstract: We present a model of a two-step solar process for producing Zn from ZnO. The process consists of the following reactions: Fe3O4(1) → 3FeO(1) + 12O2 and 3FeO(s,1) + ZnO(s) → Fe3O4(s) + Zn(g). The rate and extent of decomposition of the first reaction is limited by the rate at which O2 diffuses from the liquid-gas interface. We verified experimentally that the second reaction is possible. A theoretical study shows that the Zn yield can be controlled by temperature, pressure, and partial pressure of Zn. The maximum overall efficiency of this two-step process varies from 14 to 64% in the temperature range of 2100–2200 K.

Date: 1997
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Persistent link: https://EconPapers.repec.org/RePEc:eee:energy:v:22:y:1997:i:2:p:301-309

DOI: 10.1016/S0360-5442(96)00137-5

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