Experimental research on chemisorption energy storage performance for industrial waste heat recovery and conversion

Ye Tian, Chao Zhang, Haifeng Huang, Jiale Shen, Xiong Zhou, Lian Hu and Wensheng Ma

Energy, 2024, vol. 309, issue C

Abstract: This study investigates a solid chemisorption energy storage system utilizing a multi-component chloride salt composite adsorbent with a mass ratio of NH4Cl, CaCl2, MnCl2, and expanded natural graphite treated with sulfuric acid (ENG-TSA). The system features a shell-and-tube heat exchanger and analyzes refrigeration and heat storage performance under varying industrial low-temperature waste heat (60–110 °C) conditions, with condensation and evaporation temperatures of 0–25 °C and discharging temperatures of 40–60 °C. The results indicate that the multi-salt composite adsorbent reduces hysteresis between adsorption and desorption stages. The highest coefficient of performance (COP) and specific cooling power (SCP) were 0.461 and 328 W/kg, respectively, at an evaporation temperature of 25 °C and a charging temperature of 110 °C. Excessively long cycle times negatively affect system efficiency, with optimal performance achieved at a 40-min cycle. The findings highlight the system's effectiveness for industrial low-grade waste heat recovery, providing a solid foundation for future reactor design and material selection.

Keywords: Chemisorption; Low-temperature waste heat; Composite adsorbent; Heat storage (search for similar items in EconPapers)
Date: 2024
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Persistent link: https://EconPapers.repec.org/RePEc:eee:energy:v:309:y:2024:i:c:s0360544224029438

DOI: 10.1016/j.energy.2024.133168

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