Study for improving ammonia combustion and emissions using different hydrogen addition strategies in pre-chamber turbulent jet ignition mode

Xiangyu Meng, Wenchao Zhu, Shuo Yin, Jiangping Tian, Jianlin Cao, Wuqiang Long and Mingshu Bi

Energy, 2025, vol. 323, issue C

Abstract: The turbulent jet ignition (TJI) mode is a viable strategy to achieve high thermal efficiency and low nitrogen oxide (NOx) emissions for ammonia (NH3). In this study, the combustion behavior and NOx emissions were comprehensively compared under lean-burn condition for active TJI mode with pure NH3, active TJI mode with pre-chamber H2 addition, and passive TJI mode with NH3/H2 blend. The results indicated that the active TJI mode with the equivalence ratio (ER) of the pre-chamber increased from 0.6 to 0.9 by H2 addition produces a higher velocity jet flame that rebounds into the main chamber, substantially shortening ignition delay and initial flame duration while avoiding excessive peak heat release rates. Increasing the ER or the H2 energy ratio in the main chamber raises the flame temperature and radical concentrations. This reduces the final fuel NO and NO2 emissions while increasing thermal+prompt NO and NO2 emissions, which become dominant. In all TJI cases in this study, total N2O emissions are dominated by fuel N2O. During the early combustion stage, fuel NOx is concentrated at the flame front. In the later stage, fuel NO and NO2 are mainly distributed near the chamber wall, while fuel N2O remains close to zero. Thermal+prompt NOx is generated in high-temperature regions during the later combustion stage, declining slowly after peaking.

Keywords: Ammonia combustion; Turbulent jet ignition; Lean-burn condition; NOx emission; Isotope labeling method (search for similar items in EconPapers)
Date: 2025
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Persistent link: https://EconPapers.repec.org/RePEc:eee:energy:v:323:y:2025:i:c:s0360544225014562

DOI: 10.1016/j.energy.2025.135814

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