Key parameters of active layers affecting proton exchange membrane (PEM) fuel cell performance
Jarupuk Thepkaew,
Apichai Therdthianwong and
Supaporn Therdthianwong
Energy, 2008, vol. 33, issue 12, 1794-1800
Abstract:
The 2n full factorial design was applied to identify the key parameters of the active layer affecting the performance of a proton exchange membrane (PEM) fuel cell. Three main selected parameters were considered: carbon-type (Vulcan XC 72R and Black Pearls 2000 conducting furnace blacks, Cabot Corporation Boston, MA), Pt loading (0.1 and 0.5mg/cm2), and Nafion™ sulfonic acid fluoropolymer (Du Pont de Nemours, Wilmington, DE) ionomer content (10% and 60%) for variables A, B, and C, respectively. The results from full factorial analysis indicated that the key factors affecting the exchange current density or activation loss were Pt loading whereas the key factors controlling the resistance due to ohmic loss were Nafion content and carbon type. In addition, there are the interactions between these parameters controlling the thin-film active layer performance, especially the interaction of carbon type and Nafion content. From cyclic voltammograms and cell performance testing, a Nafion content of 30% in a catalyst layer consisting of 0.5mg/cm2 Pt on Vulcan XC 72R is optimal.
Keywords: PEMFC; Catalyst layer; Full factorial analysis; Pt loading; Nafion content; Black Pearls; Vulcan XC 72R (search for similar items in EconPapers)
Date: 2008
References: View references in EconPapers View complete reference list from CitEc
Citations: View citations in EconPapers (19)
Downloads: (external link)
http://www.sciencedirect.com/science/article/pii/S0360544208001953
Full text for ScienceDirect subscribers only
Related works:
This item may be available elsewhere in EconPapers: Search for items with the same title.
Export reference: BibTeX
RIS (EndNote, ProCite, RefMan)
HTML/Text
Persistent link: https://EconPapers.repec.org/RePEc:eee:energy:v:33:y:2008:i:12:p:1794-1800
DOI: 10.1016/j.energy.2008.08.008
Access Statistics for this article
Energy is currently edited by Henrik Lund and Mark J. Kaiser
More articles in Energy from Elsevier
Bibliographic data for series maintained by Catherine Liu ().