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Composite sorbent of methanol “LiCl in mesoporous silica gel” for adsorption cooling: Dynamic optimization

Larisa G. Gordeeva and Yuriy I. Aristov

Energy, 2011, vol. 36, issue 2, 1273-1279

Abstract: A novel composite sorbent of methanol “LiCl in mesoporous silica gel” has recently been proposed for AC (adsorption cooling). Its testing in a lab-scale adsorption chiller resulted in the specific cooling power of 210–290 W/kg and the cooling COP of 0.32–0.4. Although these values are rather encouraging, a room for their enhancement still exists. The aim of this paper was a dynamic optimization of the composite performance in AC cycles. Dynamics of methanol sorption on loose grains of the LiCl/silica composites was studied by a Large Temperature Jump method under typical conditions of AC cycle. Effects of number of the sorbent layers, salt content, grain size and cycle boundary temperatures were studied. Physico-chemical processes in the three-phase system (salt, solution, vapor) were shown to be quite complex and can strongly affect the dynamics of methanol ad-/desorption. Several obstacles which can retard the sorption were analyzed. Appropriate recommendations on improving the cycle dynamics, which concern optimal conversion degree, salt content and relative durations of ad- and desorption phases, were made.

Keywords: Adsorption cooling; LiCl/silica composite; Methanol; Adsorption dynamics (search for similar items in EconPapers)
Date: 2011
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Citations: View citations in EconPapers (17)

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Persistent link: https://EconPapers.repec.org/RePEc:eee:energy:v:36:y:2011:i:2:p:1273-1279

DOI: 10.1016/j.energy.2010.11.016

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