Development of Al2O3 carrier-Ru composite catalyst for hydrogen generation from alkaline NaBH4 hydrolysis

Yao-Hui Huang, Chia-Chi Su, Shu-Ling Wang and Ming-Chun Lu

Energy, 2012, vol. 46, issue 1, 242-247

Abstract: A recyclable and reusable Ru/Al2O3 catalyst is prepared for hydrogen generation from the hydrolysis process of alkaline sodium borohydride (NaBH4) solution. The hydrogen generation rate by the hydrolysis and methanolysis of alkaline NaBH4 was explored as a function of NaOH concentration. Meantime, the byproducts derived from the spent alkaline NaBH4 solution were characterized by X-ray diffraction (XRD), scanning electro microscope/energy dispersive spectrometer (SEM/EDS) and NMR (Nuclear Magnetic Resonance). The effect of NaOH concentration on the hydrogen generation from the hydrolysis of NaBH4 significantly depends on the type of catalysts. With increasing NaOH concentration, the hydrogen generation rates decrease when using ruthenium (Ru) composite as a catalyst. The hydrogen generation rate of the methanolysis of NaBH4 is significantly inhibited in the presence of NaOH as compared with the hydrolysis of NaBH4. The durability test of the Ru/Al2O3 catalyst shows that the hydrogen generation rate decreases with recycling and reuse. The XRD and NMR analysis results show that the borate hydrate (NaBO2 H2O) was derived from the hydrolysis of 20 wt% and 30 wt% NaBH4.

Keywords: Sodium borohydride; Hydrogen generation; Ruthenium; Methanolysis; Byproduct (search for similar items in EconPapers)
Date: 2012
References: View references in EconPapers View complete reference list from CitEc
Citations: View citations in EconPapers (14)

Downloads: (external link)
http://www.sciencedirect.com/science/article/pii/S0360544212006585
Full text for ScienceDirect subscribers only

Related works:
This item may be available elsewhere in EconPapers: Search for items with the same title.

Export reference: BibTeX RIS (EndNote, ProCite, RefMan) HTML/Text

Persistent link: https://EconPapers.repec.org/RePEc:eee:energy:v:46:y:2012:i:1:p:242-247

DOI: 10.1016/j.energy.2012.08.027

Access Statistics for this article

Energy is currently edited by Henrik Lund and Mark J. Kaiser

More articles in Energy from Elsevier
Bibliographic data for series maintained by Catherine Liu ().