Activated carbon nanotubes/polyaniline composites as supercapacitor electrodes
Seul-Yi Lee,
Ji-Il Kim and
Soo-Jin Park
Energy, 2014, vol. 78, issue C, 298-303
Abstract:
Chemically A-MWCNT (activated multiwalled carbon nanotube)/PANI (polyaniline) composites produced via ultrasonic polymerization of an aniline monomer in the presence of A-MWCNTs were investigated as potential electrode materials for supercapacitors. These composites were compared to pristine MWCNTs and MWCNT/PANI composites. The influence of the pore structure, which developed because of the polymerization process, was investigated by measuring N2 adsorption/desorption isotherms at 77 K. The electrochemical properties of the materials were determined by cyclic voltammetry and galvanostatic charge–discharge cycling measurements in 1 M NaNO3 electrolyte solution, using a three-electrode system at room temperature. The results suggested that the pore structure of the A-MWCNTs could effectively promote the homogenous-dispersion of aniline and consequently result in excellent cycling performance. Furthermore, interaction between the π-conjugated structure of carbon and the quinoid ring of the PANI matrix can lead to enhancement in the charge transfer process.
Keywords: Activated multi-walled carbon nanotubes; Supercapacitors; Polyaniline; Nanocomposites (search for similar items in EconPapers)
Date: 2014
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Citations: View citations in EconPapers (8)
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Persistent link: https://EconPapers.repec.org/RePEc:eee:energy:v:78:y:2014:i:c:p:298-303
DOI: 10.1016/j.energy.2014.10.011
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