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Justifying the significance of Knudsen diffusion in solid oxide fuel cells

Fei Yang, Jianmin Gu, Luhan Ye, Zuoxiang Zhang, Gaofeng Rao, Yachun Liang, Kechun Wen, Jiyun Zhao, John B. Goodenough and Weidong He

Energy, 2016, vol. 95, issue C, 242-246

Abstract: Developing an appropriate diffusion mechanism to analyze the gas transport in porous electrodes of SOFCs (solid oxide fuel cells), has been a crucial step towards analyzing accurately the cell performance. In this report, the errors in evaluating the gas diffusivity, limiting current density and concentration polarization, are calculated quantitatively by taking bulk diffusion and the previously-overlooked Knudsen diffusion into account. In particular, this work analyzes the deviation between ignoring and considering the Knudsen diffusion of hydrogen transport in SOFC anodes. The study facilitates the rational pre-evaluation of micro- and nanoscale materials prior to assembly into SOFCs.

Keywords: Solid oxide fuel cells; Gas diffusion; Anode; Limiting current density; Concentration polarization (search for similar items in EconPapers)
Date: 2016
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Citations: View citations in EconPapers (3)

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Persistent link: https://EconPapers.repec.org/RePEc:eee:energy:v:95:y:2016:i:c:p:242-246

DOI: 10.1016/j.energy.2015.12.022

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