Theoretical study of the electric field effect on ion-molecule reactions in diluted gases and solutions

Wolfgang Stiller and Wolfgang Naumann

Physica A: Statistical Mechanics and its Applications, 1980, vol. 101, issue 1, 265-274

Abstract: In diluted gases the rate coefficients of ion-molecule reactions in an electric field depend on the characteristic ratio EPkBΘ where EP represents the energetic threshold for the reaction and kBΘ is the mean kinetic energy summarizing both electric field effects and collision processes within a two-temperature model. Using the Lorentz-gas concept the model can be precised from a microscopic point of view by solving a kinetic equation for the ionic component.

Date: 1980
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Persistent link: https://EconPapers.repec.org/RePEc:eee:phsmap:v:101:y:1980:i:1:p:265-274

DOI: 10.1016/0378-4371(80)90113-2

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