Non-equilibrium thermodynamics of interfacial systems

Jeffrey Kovac

Physica A: Statistical Mechanics and its Applications, 1981, vol. 107, issue 2, 280-298

Abstract: The theory of non-equilibrium thermodynamics is applied to a system of two immiscible fluids whose molecules possess internal angular momentum (spin) which are separated by an interface. The conservation laws and the Gibbs relation are used to derive the entropy production at the interface. The resulting linear laws relating the fluxes and forces represent boundary conditions on the hydrodynamic equations for the bulk phases. A limiting case is considered and boundary conditions derived by previous authors are obtained.

Date: 1981
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Citations: View citations in EconPapers (2)

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Persistent link: https://EconPapers.repec.org/RePEc:eee:phsmap:v:107:y:1981:i:2:p:280-298

DOI: 10.1016/0378-4371(81)90089-3

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