Internal field correction in far-infrared absorption of highly polar liquids

G. Bossis

Physica A: Statistical Mechanics and its Applications, 1982, vol. 110, issue 3, 408-430

Abstract: The total integrated intensity of the far-infrared absorption of highly polar liquids is analysed. It is shown that the discrepancy already observed between the theoretical result given by the Gordon sum rule corrected by the Polo Wilson internal field factor, and the experimental result, can be explained by taking into account the shape and the polarisability tensor of the molecule. New experimental results on pure liquid C5H5N and CH3CN and dilutions of C5H5N into benzene are presented. The experimental integrated absorption of these compounds and of some previously studied liquids agree well with our theoretical determination.

Date: 1982
References: View complete reference list from CitEc
Citations:

Downloads: (external link)
http://www.sciencedirect.com/science/article/pii/0378437182900607
Full text for ScienceDirect subscribers only. Journal offers the option of making the article available online on Science direct for a fee of $3,000

Related works:
This item may be available elsewhere in EconPapers: Search for items with the same title.

Export reference: BibTeX RIS (EndNote, ProCite, RefMan) HTML/Text

Persistent link: https://EconPapers.repec.org/RePEc:eee:phsmap:v:110:y:1982:i:3:p:408-430

DOI: 10.1016/0378-4371(82)90060-7

Access Statistics for this article

Physica A: Statistical Mechanics and its Applications is currently edited by K. A. Dawson, J. O. Indekeu, H.E. Stanley and C. Tsallis

More articles in Physica A: Statistical Mechanics and its Applications from Elsevier
Bibliographic data for series maintained by Catherine Liu ().