Theoretical description of the methyl group relaxation in liquids

Barbara Blicharska

Physica A: Statistical Mechanics and its Applications, 1988, vol. 147, issue 3, 601-626

Abstract: Spin-lattice and spin-spin relaxation times of protons and deuterons of methyl groups in liquids are calculated using a semiclassical form of the density operator formalism and symmetry adapted spherical tensors. The model of molecular motion assumes diffusion of the whole molecule containing the methyl group with some internal rotation. Special consideration is given to uniaxial internal rotation and anisotropic diffusion as well as to biaxial internal rotation and isotropic diffusion in interpreting the experimental results.

Date: 1988
References: View references in EconPapers View complete reference list from CitEc
Citations:

Downloads: (external link)
http://www.sciencedirect.com/science/article/pii/0378437188901720
Full text for ScienceDirect subscribers only. Journal offers the option of making the article available online on Science direct for a fee of $3,000

Related works:
This item may be available elsewhere in EconPapers: Search for items with the same title.

Export reference: BibTeX RIS (EndNote, ProCite, RefMan) HTML/Text

Persistent link: https://EconPapers.repec.org/RePEc:eee:phsmap:v:147:y:1988:i:3:p:601-626

DOI: 10.1016/0378-4371(88)90172-0

Access Statistics for this article

Physica A: Statistical Mechanics and its Applications is currently edited by K. A. Dawson, J. O. Indekeu, H.E. Stanley and C. Tsallis

More articles in Physica A: Statistical Mechanics and its Applications from Elsevier
Bibliographic data for series maintained by Catherine Liu ().