A probabilistic analysis of the Walker-Vause model for liquid binary mixtures

J. Güémez, A. Calvo Hernández, S. Velasco and E. Combariza

Physica A: Statistical Mechanics and its Applications, 1988, vol. 152, issue 3, 384-399

Abstract: A simple method to calculate the probability distribution for a binary fluid mixture is presented. The method is applid to the Walker-Vause binary liquid model and different temperature vs composition phase diagrams are obtained. These diagrams are obtained using catastrophe theory methods. Comparison with some experimental data are also discussed and a simplified model leading to closed-loop phase diagrams is considered.

Date: 1988
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Citations: View citations in EconPapers (2)

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Persistent link: https://EconPapers.repec.org/RePEc:eee:phsmap:v:152:y:1988:i:3:p:384-399

DOI: 10.1016/0378-4371(88)90195-1

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