Transport properties of dense fluids via spherical models of the interaction potential

V.F. Nebelenchuk and V.A. Mazur

Physica A: Statistical Mechanics and its Applications, 1991, vol. 178, issue 1, 123-148

Abstract: The method for evaluation of the dense fluid viscosity and thermal conductivity (translational part) from intermolecular interaction information is derived on the basis of the local similarity principle. The non-equilibrium criteria of mapping a real-system interaction function Ur(R) to the reference Van der Waals potential Ub(R, A) are formulated first. Then the density dependence for the kinetic effective hard-sphere diameter is studied. The test of the proposed approach has been carried out for a number of spherical potential models (Ne-Ne, Ar-Ar, Kr-Kr, Xe-Xe, CO2-CO2, N2-N2, O2-O2) in the range of the reduced densities 0.4Date: 1991
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Persistent link: https://EconPapers.repec.org/RePEc:eee:phsmap:v:178:y:1991:i:1:p:123-148

DOI: 10.1016/0378-4371(91)90077-P

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