Macroscopic laws, microscopic dynamics, time's arrow and Boltzmann's entropy
Joel L. Lebowitz
Physica A: Statistical Mechanics and its Applications, 1993, vol. 194, issue 1, 1-27
Abstract:
I discuss Boltzmann's resolution of the apparent paradox: microscopic dynamics are time-symmetric but the behavior of macroscopic objects, composed of microscopic constituents, is time-asymmetric. Noting the great disparity between macroscales and microscales Boltzmann developed a statistical approach which explains the observed macroscopic behavior. In particular it predicts the increase with time of the “Boltzmann entropy”, SB(X), for “almost all” microscopic states X, of a nonequilibrium macroscopic system. The quantitative description of the macroscopic evolution, and ipso facto the compatibility between the macroscopic descriptions and microscopic descriptions, is illustrated by an example: the rigorous derivation of a diffusion equation for the typical macroscopic density profile of a Lorentz gas of independent electrons moving according to Hamiltonian dynamics. The role of low entropy “initial states” is emphasized.
Date: 1993
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Citations: View citations in EconPapers (4)
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Persistent link: https://EconPapers.repec.org/RePEc:eee:phsmap:v:194:y:1993:i:1:p:1-27
DOI: 10.1016/0378-4371(93)90336-3
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