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Anomalies in the scaling of the α-relaxation studied by dielectric spectroscopy

A. Schönhals, F. Kremer, A. Hofmann and E.W. Fischer

Physica A: Statistical Mechanics and its Applications, 1993, vol. 201, issue 1, 263-269

Abstract: The scaling of the α-relaxation for propylene carbonate, glycerol and propylene glycol is evaluated by broadband dielectric spectroscopy in a frequency range from 10-5 Hz to 1010 Hz. At low temperature the mean relaxation frequency ƒp follows the well-known Vogel-Fulcher-Tamann law whereas at high temperatures ƒp can be described by an Arrhenius law or by a power law predicted by the mode coupling theory. Both regions can be separated by a crossover temperature. Also the dielectric relaxation strength shows approximately in this temperature range a change in their temperature dependencies.

Date: 1993
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Persistent link: https://EconPapers.repec.org/RePEc:eee:phsmap:v:201:y:1993:i:1:p:263-269

DOI: 10.1016/0378-4371(93)90421-Y

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