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Onset of the dynamic glass transition in poly(n butyl methacrylate)

M. Beiner, F. Garwe, E. Hempel, J. Schawe, K. Schröter, A. Schönhals and E. Donth

Physica A: Statistical Mechanics and its Applications, 1993, vol. 201, issue 1, 72-78

Abstract: Specific heat Cp, dynamic shear modulus G∗, and dielectric compliance ε∗ are measured in the splitting region a ↔ α + β of poly(n butyl methacrylate). The characteristic length of the glass transition is estimated from the calorimetric data to be about one nanometer before the breakdown of cooperativity between 15 and 21°C. The merging of the dielectric α and β traces is between 70 and 80°C, more than fifty degrees higher.

Date: 1993
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Persistent link: https://EconPapers.repec.org/RePEc:eee:phsmap:v:201:y:1993:i:1:p:72-78

DOI: 10.1016/0378-4371(93)90401-O

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