Density profiles of associating fluid near a hard wall: PY/EMSA and HNC/EMSA singlet theory

S. Sokołowski, D. Henderson, A. Trokhymchuk and O. Pizio

Physica A: Statistical Mechanics and its Applications, 1995, vol. 220, issue 1, 24-32

Abstract: A two-component model of hard spheres with a spherically symmetric associative interaction between the particles of different species near a hard wall is studied by suing the integral equation method. It is shown that the extended mean spherical approximation for the bulk associating fluid in conjunction with the Percus-Yevick closure of the singlet level theory of inhomogeneous fluid leads to very good agreement of theoretical density profiles with simulation data for highly associated fluid at a high bulk density.

Date: 1995
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Persistent link: https://EconPapers.repec.org/RePEc:eee:phsmap:v:220:y:1995:i:1:p:24-32

DOI: 10.1016/0378-4371(95)00119-R

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