Violation of the electroneutrality condition in confined unsymmetrical electrolytes

Marcelo Lozada-Cassou, Wilmer Olivares, Belky Sulbarán and Yu Jiang

Physica A: Statistical Mechanics and its Applications, 1996, vol. 231, issue 1, 197-206

Abstract: The three-point extension hypernetted chain-mean spherical theory of liquids is solved for a system formed by two charged plates immersed in a model unsymmetrical electrolyte. The charge on the plates is fixed as a function of the distance between the plates. The extent to which the local electroneutrality condition is not satisfied is studied. The plate-plate force is calculated and compared to that for confined symmetrical electrolytes.

Date: 1996
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Persistent link: https://EconPapers.repec.org/RePEc:eee:phsmap:v:231:y:1996:i:1:p:197-206

DOI: 10.1016/0378-4371(95)00451-3

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