Kinetic equation for liquids with a multistep potential of interaction. H-theorem
I.P. Omelyan and
M.V. Tokarchuk
Physica A: Statistical Mechanics and its Applications, 1996, vol. 234, issue 1, 89-107
Abstract:
A new kinetic equation for dense gases and liquids with the interparticle potential of interaction in a form of the multistep function is proposed. The equation is consistently derived on the basis of Zubarev's nonequilibrium statistical operator method using a modification for weakening correlations principle which takes into account local conservation laws. In particular cases this equation coincides with the well known kinetic equations for hard-sphere and square-well potentials. Application of the obtained kinetic equation to real systems is discussed. A proof of a global H-theorem is given.
Keywords: Kinetic equation; Dense gases; Multistep potential; Boundary condition; H-theorem (search for similar items in EconPapers)
Date: 1996
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Persistent link: https://EconPapers.repec.org/RePEc:eee:phsmap:v:234:y:1996:i:1:p:89-107
DOI: 10.1016/S0378-4371(96)00286-5
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