Reversible diffusion-controlled reactions in a colloidal kinetic Ising model

B.U. Felderhof and R.B. Jones

Physica A: Statistical Mechanics and its Applications, 1997, vol. 240, issue 1, 188-192

Abstract: The time-dependence of reversible diffusion-controlled reactions in a binary suspension of equal-sized spheres is studied on the basis of the time-correlation matrix of concentration fluctuations in thermal equilibrium. The transient effects are calculated in an Enskog-type approximation from the nonequilibrium distribution function of a pair of diffusing and mutating spheres. The equilibrium radial distribution functions of the system are assumed to be sufficiently well known. The calculation yields predictions of the time-correlation matrix of concentration fluctuations, which can be compared with computer simulations of the model system.

Date: 1997
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Persistent link: https://EconPapers.repec.org/RePEc:eee:phsmap:v:240:y:1997:i:1:p:188-192

DOI: 10.1016/S0378-4371(97)00140-4

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