Electrolytes confined to a plane in the Debye-Hückel theory

Esov S. Velázquez and Lesser Blum

Physica A: Statistical Mechanics and its Applications, 1997, vol. 244, issue 1, 453-460

Abstract: An electroneutral system of charged hard three-dimensional spheres confined to a two-dimensional plane is studied in the linearized Poisson-Boltzmann approximation. This system can be considered a model for ions on a membrane or ions adsorbed at an electrode. The extreme coupling limits are studied and the Onsager condition for infinite coupling, TΔS/ΔE → 0, is shown to be satisfied.

Date: 1997
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Persistent link: https://EconPapers.repec.org/RePEc:eee:phsmap:v:244:y:1997:i:1:p:453-460

DOI: 10.1016/S0378-4371(97)00248-3

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