Living poly(α-methylstyrene) near the polymerization line 6. Chemical kinetics

Juewen Zhuang, S. Sarkar Das, M.D. Nowakowski and S.C. Greer

Physica A: Statistical Mechanics and its Applications, 1997, vol. 244, issue 1, 522-535

Abstract: We present new measurements of the kinetics of polymerization near the polymerization line of poly(α-methylstyrene) in the solvent tetrahydrofuran, initiated by sodium naphthalide or cesium naphthalide. We develop a computer model of the kinetics of the reversible polymerization of this system. We fit the model to the experimental data to obtain rate constants for propagation and depropagation.

Date: 1997
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Persistent link: https://EconPapers.repec.org/RePEc:eee:phsmap:v:244:y:1997:i:1:p:522-535

DOI: 10.1016/S0378-4371(97)00242-2

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