Diameters of rotationally and vibrationally excited diatomic molecules

Yuriy E. Gorbachev, Francisco J. Gordillo-Vázquez and Joseph A. Kunc

Physica A: Statistical Mechanics and its Applications, 1997, vol. 247, issue 1, 108-120

Abstract: Analytical expressions for kinetic diameters of rotationally and vibrationally excited diatomic molecules are derived using the Hamilton-Jacoby theory and the Bohr-Sommerfeld quantization rule. The diameters are obtained assuming the rotating Morse and Tietz-Hua oscillators as dynamical models of the molecules.

Date: 1997
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Persistent link: https://EconPapers.repec.org/RePEc:eee:phsmap:v:247:y:1997:i:1:p:108-120

DOI: 10.1016/S0378-4371(97)00389-0

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