The effect of chemical displacement of B species in the reaction A+B→B

A.A. Kipriyanov, O.A. Igoshin and A.B. Doktorov

Physica A: Statistical Mechanics and its Applications, 2000, vol. 275, issue 1, 99-133

Abstract: The non-Markovian binary kinetic equations of the irreversible reaction A+B→B taking into account B reactant displacement due to chemical conversion events have been derived for the first time. The derivation is based on the many-particle closure method recently proposed by the authors. It is shown that a conventional view of the reaction A+B→B as a pseudomonomolecular reaction is true only for spatially uniform systems. In the case of spatially non-uniform systems additional macroscopic flows arise. They can transform an originally uniform distribution of one of the species into a non-uniform one in the course of the reaction.

Date: 2000
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Persistent link: https://EconPapers.repec.org/RePEc:eee:phsmap:v:275:y:2000:i:1:p:99-133

DOI: 10.1016/S0378-4371(99)00396-9

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