Consideration of initial correlations of the same type in reactions A+B→B and A+B→C+B

A.A. Kipriyanov and A.B. Doktorov

Physica A: Statistical Mechanics and its Applications, 2000, vol. 286, issue 1, 109-132

Abstract: A new method is used to derive the binary non-markovian integro-differential kinetic equations of irreversible reactions with respect to initial correlations of the same type. The source of inhomogeneous integro-differential equation is determined by initial correlations which is in full accord with the properties of kinetic equations of non-equilibrium statistical mechanics. A procedure is found to reduce the derived equations into the differential form of the equations of chemical kinetics.

Date: 2000
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Persistent link: https://EconPapers.repec.org/RePEc:eee:phsmap:v:286:y:2000:i:1:p:109-132

DOI: 10.1016/S0378-4371(00)00190-4

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