Non-Markovian kinetic equations of dissociation and reversible reaction A+B⇄C in solutions

A.B. Doktorov and A.A. Kipriyanov

Physica A: Statistical Mechanics and its Applications, 2003, vol. 317, issue 1, 41-62

Abstract: A consistent many-particle approach has been used to derive integro-differential kinetic equations of a bulk reaction of dissociation in spatially non-uniform solutions in a hydrodynamic approximation with a realistic description of reactants structure and translational mobility. The detailed analysis of the memory function structure of this equation has been carried out, and a microscopic detailed balancing principle of the theory of migration accelerated reactions has been formulated. This has made it possible to formulate a macroscopic kinetic detailed balancing principle for non-Markovian dissociation and recombination kinetics. The non-Markovian kinetic equation of the reversible reaction A+B⇄C in spatially non-uniform systems is proposed. Thermodynamic detailed balancing principle is established.

Keywords: Kinetic equations; Many-particle approach; Elementary reactions; The law of mass action (search for similar items in EconPapers)
Date: 2003
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Persistent link: https://EconPapers.repec.org/RePEc:eee:phsmap:v:317:y:2003:i:1:p:41-62

DOI: 10.1016/S0378-4371(02)01324-9

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