A many-particle derivation of non-Markovian kinetic equations of reversible reaction A+B⇌C in solutions based on the effective pairs approach

A.A. Kipriyanov and A.B. Doktorov

Physica A: Statistical Mechanics and its Applications, 2003, vol. 326, issue 1, 105-128

Abstract: The non-Markovian kinetic equations for local concentrations have been derived in the effective pairs approximation on the basis of the hierarchy for correlation patterns of the reversible reaction A+B⇌C. The equations are shown to agree with the kinetic and thermodynamic detailed balancing principles. As compared to the integral encounter theory equations obtained earlier, the above equations have a wider time range of applicability, and may form the basis for the development of a binary approximation for the reversible reaction A+B⇌C in solutions.

Keywords: Kinetic equations; Many-particle approach; Elementary reactions; Law of mass action; Diagram technique (search for similar items in EconPapers)
Date: 2003
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Persistent link: https://EconPapers.repec.org/RePEc:eee:phsmap:v:326:y:2003:i:1:p:105-128

DOI: 10.1016/S0378-4371(03)00288-7

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