Adsorption thermodynamics of interacting particles on diffusion-limited aggregates

M. Nazzarro, F. Nieto and A.J. Ramirez-Pastor

Physica A: Statistical Mechanics and its Applications, 2004, vol. 331, issue 3, 517-530

Abstract: Grand canonical Monte Carlo simulations have been performed in order to study adsorption thermodynamics of pairwise interacting particles on fractal surfaces. Diffusion-limited aggregates (DLA) have been used as a substrate where interacting particles are adsorbed. In order to obtain aggregates with different morphologies, DLA clusters are generated on different strongly correlated surfaces. Adsorption isotherm, adsorption energy and differential heat of adsorption were calculated for attractive and repulsive nearest-neighbor (NN) lateral interactions. For the case of repulsive couplings and low temperatures, four novel ordered phases has been found in the adsorbate, each one corresponding to the formation of a chessboard-like structure on sites with one, two, three and four NN sites, respectively. The values of coverage at which these ordered phases emerge are not symmetrical around θ=0.5. This is a consequence of the non-equivalence between vacancy and particle in the case of adsorption on fractal structures. The influence of ordered structures on thermodynamic quantities associated to the adsorbed monolayer has been analyzed and discussed in the context of the Lattice-Gas model.

Keywords: Adsorption; Fractals; Computer simulations; Monte Carlo method (search for similar items in EconPapers)
Date: 2004
References: View complete reference list from CitEc
Citations:

Downloads: (external link)
http://www.sciencedirect.com/science/article/pii/S0378437103008720
Full text for ScienceDirect subscribers only. Journal offers the option of making the article available online on Science direct for a fee of $3,000

Related works:
This item may be available elsewhere in EconPapers: Search for items with the same title.

Export reference: BibTeX RIS (EndNote, ProCite, RefMan) HTML/Text

Persistent link: https://EconPapers.repec.org/RePEc:eee:phsmap:v:331:y:2004:i:3:p:517-530

DOI: 10.1016/j.physa.2003.09.030

Access Statistics for this article

Physica A: Statistical Mechanics and its Applications is currently edited by K. A. Dawson, J. O. Indekeu, H.E. Stanley and C. Tsallis

More articles in Physica A: Statistical Mechanics and its Applications from Elsevier
Bibliographic data for series maintained by Catherine Liu ().