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A theorem on the equilibrium thermodynamics of Hamiltonian systems

Antonio Ponno

Physica A: Statistical Mechanics and its Applications, 2006, vol. 359, issue C, 162-176

Abstract: We prove a theorem stating that, within an interesting class of stationary solutions of the Liouville equation, the Tsallis q-distributions are the only ones that satisfy a condition which guarantees the existence of an integrating factor for the heat. The functional forms of the distribution as well as that of entropy, temperature and heat capacity are derived. We then explain why the Gibbs distribution, as a limit of the Tsallis one, plays a privileged role for large size ordinary molecular systems.

Keywords: Tsallis statistics; Thermodynamics of Hamiltonian systems (search for similar items in EconPapers)
Date: 2006
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Persistent link: https://EconPapers.repec.org/RePEc:eee:phsmap:v:359:y:2006:i:c:p:162-176

DOI: 10.1016/j.physa.2005.04.042

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Physica A: Statistical Mechanics and its Applications is currently edited by K. A. Dawson, J. O. Indekeu, H.E. Stanley and C. Tsallis

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