Thermodynamics with generalized ensembles: The class of dual orthodes

Michele Campisi

Physica A: Statistical Mechanics and its Applications, 2007, vol. 385, issue 2, 501-517

Abstract: We address the problem of the foundation of generalized ensembles in statistical physics. The approach is based on Boltzmann's concept of orthodes. These are the statistical ensembles that satisfy the heat theorem, according to which the heat exchanged divided by the temperature is an exact differential. This approach can be seen as a mechanical approach alternative to the well established information-theoretic one based on the maximization of generalized information entropy. Our starting point are the Tsallis escort ensembles which have been previously proved to be orthodes, and have been proved to interpolate between canonical and microcanonical ensembles. Here we shall see that the Tsallis escort ensembles belong to a wider class of orthodes that include the most diverse types of ensembles. All such ensembles admit both a microcanonical-like parametrization (via the energy), and a canonical-like one (via the parameter β). For this reason we name them “dual”. One central result used to build the theory is a generalized equipartition theorem. The theory is illustrated with a few examples and the equivalence of all the dual orthodes is discussed.

Keywords: Generalized thermostatistics; Heat theorem; Ensemble theory; Canonical; Microcanonical; Tsallis; Gaussian (search for similar items in EconPapers)
Date: 2007
References: View references in EconPapers View complete reference list from CitEc
Citations:

Downloads: (external link)
http://www.sciencedirect.com/science/article/pii/S0378437107007601
Full text for ScienceDirect subscribers only. Journal offers the option of making the article available online on Science direct for a fee of $3,000

Related works:
This item may be available elsewhere in EconPapers: Search for items with the same title.

Export reference: BibTeX RIS (EndNote, ProCite, RefMan) HTML/Text

Persistent link: https://EconPapers.repec.org/RePEc:eee:phsmap:v:385:y:2007:i:2:p:501-517

DOI: 10.1016/j.physa.2007.07.004

Access Statistics for this article

Physica A: Statistical Mechanics and its Applications is currently edited by K. A. Dawson, J. O. Indekeu, H.E. Stanley and C. Tsallis

More articles in Physica A: Statistical Mechanics and its Applications from Elsevier
Bibliographic data for series maintained by Catherine Liu ().