Formal study of a chemical reaction by Grad expansion of the Boltzmann equation. I

M. Moreau

Physica A: Statistical Mechanics and its Applications, 1975, vol. 79, issue 1, 18-38

Abstract: The Boltzmann equations for a formal bimolecular chemical reaction in homogeneous gas phase are transformed into an infinite system of quadratic differential equations, by expanding the distribution functions of the molecules into the Grad polynomials. The properties of these expanded Boltzmann equations reflect the macroscopic laws. In particular they enable the Onsager reciprocity relations to be derived from time-reversal invariance.

Date: 1975
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Persistent link: https://EconPapers.repec.org/RePEc:eee:phsmap:v:79:y:1975:i:1:p:18-38

DOI: 10.1016/0378-4371(75)90085-0

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