Dielectric alignment of a non-polar molecule substituting a polar molecule in a lattice of molecular dipoles

J. Biemond

Physica A: Statistical Mechanics and its Applications, 1977, vol. 88, issue 2, 385-394

Abstract: The dielectric alignment of a dilute non-polar component in a polar solvent may be determined by NMR spectroscopy. In this paper a series expansion of the alignment up to second order terms in the dipolar interaction is presented for a non-polar molecule replacing a single polar molecule in a rigid lattice of molecular dipoles. Assuming isotropic polarizabilities for all molecules Van Vleck earlier applied the lattice model in a theory of the dielectric constant of a dilute solution.

Date: 1977
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Persistent link: https://EconPapers.repec.org/RePEc:eee:phsmap:v:88:y:1977:i:2:p:385-394

DOI: 10.1016/0378-4371(77)90012-7

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