The influence of chain-flexibility on the colligative properties of polyelectrolyte solutions

Theo Odijk and M. Mandel

Physica A: Statistical Mechanics and its Applications, 1978, vol. 93, issue 1, 298-306

Abstract: The neglect of chain flexibility in Manning's theory of polyelectrolytes is assessed. For a flexible polyelectrolyte-the uniformly charged wormlike chain-counterion condensation is unaffected but colligative properties need to be modified. The relevant dimensionless parameter is (κLT)-1 where κ-1 is the Debye-Hückel radius and LT is the sum of the bare and electrostatic persistence lengths.

Date: 1978
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Persistent link: https://EconPapers.repec.org/RePEc:eee:phsmap:v:93:y:1978:i:1:p:298-306

DOI: 10.1016/0378-4371(78)90223-6

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