Use of accurate diffusion and second virial coefficients to determine (m, 6, 8) potential parameters for nine binary noble gas systems

P.S. Arora, H.L. Robjohns and Peter J. Dunlop

Physica A: Statistical Mechanics and its Applications, 1979, vol. 95, issue 3, 561-571

Abstract: Using accurate binary diffusion coefficients obtained over a temperature range of 275 to 323 K, together with some excellent second virial coefficients in the literature, (m, 6, 8) potential parameters have been obtained for the systems He-Ne, He-Ar, He-Kr, He-Xe, Ne-Ar, Ne-Kr, Ne-Xe, Ar-Kr and Ar-Xe. These parameters accurately predict all the precise binary transport properties which have been reported for these systems, some over a range of 1400 K. The present analysis indicates that these mixtures are not conformal with any one of the assumed (m, 6, 8) group of potentials.

Date: 1979
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Persistent link: https://EconPapers.repec.org/RePEc:eee:phsmap:v:95:y:1979:i:3:p:561-571

DOI: 10.1016/0378-4371(79)90032-3

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