Enhanced photoelectrochemical performance of TiO2 photoanode decorated with Pd-carbon core shell nanoparticles

Rishabh Sharma, Nisha Kodan, Vinod Singh, Shailesh Narayan Sharma and Om Prakash Sinha

Renewable Energy, 2019, vol. 134, issue C, 1232-1239

Abstract: In this work, we report enhancement in photoelectrochemical performance of TiO2 photo-anode on coating it with Palladium carbon (Pd-C) core shell nanoparticles. Transmission electron microscopy images confirmed formation of Pd nanoparticle and Pd-C nanoparticles with Pd core surrounded by carbon shell. X-Ray Diffraction analysis confirmed the pure anatase phase of synthesized TiO2 films. Raman spectroscopy revealed graphitic nature of carbon in Pd-C. In comparison to pristine TiO2, quenching in PL intensity of Pd-TiO2& Pd-C-TiO2 sample was observed which indicates lowering of recombination rate of charge carriers, this effect is explained through surface plasmon resonance (SPR) in Pd and Pd-C nanoparticles. Also, SPR in Pd & Pd-C promoted absorption of photons in visible region thus making both Pd-C-TiO2& Pd-TiO2 active in visible region. Finally, graphitic carbon layer over Pd in Pd-C-TiO2 offered an additional advantage over bare Pd in Pd-TiO2 i.e. reducing the charge transfer resistance between electrode and electrolyte under illumination.

Keywords: Photoelectrochemical; Surface plasmon resonance; Pd nanoparticles; Core-shell (search for similar items in EconPapers)
Date: 2019
References: View complete reference list from CitEc
Citations: View citations in EconPapers (2)

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Persistent link: https://EconPapers.repec.org/RePEc:eee:renene:v:134:y:2019:i:c:p:1232-1239

DOI: 10.1016/j.renene.2018.09.061

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