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Bulk features of catalytic co-pyrolysis of sugarcane bagasse and a hydrogen-rich waste: The case of waste heavy paraffin

Masoumeh Kouhi and Kayghobad Shams

Renewable Energy, 2019, vol. 140, issue C, 970-982

Abstract: In this study, catalytic and non-catalytic pyrolysis and co-pyrolysis of pretreated and intact sugarcane bagasse was investigated using waste heavy paraffin (as an in-situ supply of hydrogen). A Y-type commercial zeolite catalyst (HGY-A) which is a gasoline boosting catalyst suitable for hydrocracking reactions in oil refining was used for catalytic pyrolysis. Co-feeding of bagasse with paraffin produced higher liquid product yields and lower solid yields. The improved effective hydrogen to carbon ratio (H/Ceff) of the feedstock, and primary cracking and fragmentation reactions of heavy paraffin at temperatures around 600 °C are responsible for considerable improvement of bio-oil yield. Use of HGY-A catalyst did change the composition of the produced bio-oil; however, it did not have any appreciable impact on the bio-oil yield under various operational conditions. Results showed that acidic pretreatment of bagasse (with a 30% w/w HCl) reduced the bio-oil yield and increased the char yield.

Keywords: Sugarcane bagasse; Heavy waste paraffin; Co-pyrolysis; Pretreatment; Zeolite catalyst; Bio-oil (search for similar items in EconPapers)
Date: 2019
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Citations: View citations in EconPapers (1)

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Persistent link: https://EconPapers.repec.org/RePEc:eee:renene:v:140:y:2019:i:c:p:970-982

DOI: 10.1016/j.renene.2019.03.115

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