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Slow pyrolysis of Defatted Seeds Cakes of African star apple and silk cotton for production of bio-oil

Muhammad Abdullahi Sokoto, Bijoy Biswas, Jitendra Kumar and Thallada Bhaskar

Renewable Energy, 2020, vol. 146, issue C, 1710-1716

Abstract: The prospect of de-oiled seed cakes of African star apple (ASA) and Silk cotton (SCS) as a source of bio-oil was investigated using slow pyrolysis. The study was carried out at a temperatures range of 300–450 °C with a heating rate of 10 °C min−1 for 60 min residence period in a nitrogen atmosphere. The optimum bio-oil yields for SCS (33.1%) and for ASA (48.3%) were achieved at 400 °C. The Bio-char yield decreases from 300 °C to 450 °C (38%–28%) for ASA seedcake which could be due to greater primary decomposition of the biomass samples. A similar trend also observed for SCS with a lowest bio-char yield of 32% at 450 °C. The GC-MS analysis showed that ASA bio-oil has an acids (25.15%), phenolics (18.35%), and hydrocarbons (18.58%) as the major compounds. N-containg compounds (38.17%), carboxylic acid (23.79%), and phenolic (16.57%) were the dominant compounds in SCS bio-oil. The FT-IR absorption peak showed at 1660 cm−1 (C = N stretching) with higher intensity for SCS bio-oil. At optimum temperature 400 °C, 72% of ASA feedstock was converted into bio-oil and gaseous products (conversion), while 68% conversion was obtained from SCS at optimum temperature 400 °C.

Keywords: Pyrolysis; Silk cottonseed; African star apple; Bio-oil; Bio-char (search for similar items in EconPapers)
Date: 2020
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Citations: View citations in EconPapers (2)

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Persistent link: https://EconPapers.repec.org/RePEc:eee:renene:v:146:y:2020:i:c:p:1710-1716

DOI: 10.1016/j.renene.2019.07.145

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