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Organosulfonic acid functionalized montmorillonites as solid catalysts for (trans) esterification of free fatty acids and (waste) oils

Sónia M. Silva, Andreia F. Peixoto and Cristina Freire

Renewable Energy, 2020, vol. 146, issue C, 2416-2429

Abstract: Organosulfonic acid functionalized montemorillonite-MMT (K10 and cloisite Na+) were prepared by different methodologies: (a) one-pot organosilylation or sulfonation, and (b) two-step organosilylation followed by sulfonation or oxidation. The physicochemical characterization ensured the success of the selected methodologies to promote HSO3-functionalization including high S contents (2.84 mmol S/g) and acidities up to 6.03 mmol H+/g (K10_PhSO3H).

Keywords: Montmorillonite; K10; Cloisite; Organosilane; Esterification; Biodiesel; Organosulfonic acid solid catalysts (search for similar items in EconPapers)
Date: 2020
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Citations: View citations in EconPapers (1)

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Persistent link: https://EconPapers.repec.org/RePEc:eee:renene:v:146:y:2020:i:c:p:2416-2429

DOI: 10.1016/j.renene.2019.08.073

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