Porous carbon particles as metal-free superior catalyst for hydrogen release from methanolysis of sodium borohydride

Sahin Demirci, Mustafa Yildiz, Erk Inger and Nurettin Sahiner

Renewable Energy, 2020, vol. 147, issue P1, 69-76

Abstract: Carbon materials can be readily prepared from wood derivatives, monosaccharaides such as pentose/hexose and/or polysaccharides in addition to many starting materials by treatment of thermal, chemical and hydrothermal methods. Here, the porous carbon (PC) particles were prepared by removal of silica particles from previously prepared carbon-silica composites by hydrothermal and carbonization process from sucrose. Then, PC particles were modified with polyethyleneimine (PEI) to prepared amine functionalized PC-PEI particles and protonated with hydrochloric acid, PC-PEI+. Finally, these prepared carbon-based particles were used as catalyst for H2 release from NaBH4 methanolysis and PC-PEI+ was found as the most effective catalyst at 25 °C with 4040 ± 126 mL H2. min−1.g−1 HGR value. The Ea value of 23.9 kJ/mol in H2 release reaction from NaBH4 methanolysis catalyzed by PC-PEI+ that is comparable and/or better than most of studies reported in literature. The activity% of PC-PEI+ catalyst was 72% after fifth consequential runs. Additionally, the regeneration ability of PC-PEI+ catalyst was also shown that after fifth regeneration process, there is only 5% decrease in activity%.

Keywords: Porous carbon particle; Amine modified carbon particle; Metal-free catalyst; Carbon-based catalyst; H2 production (search for similar items in EconPapers)
Date: 2020
References: View references in EconPapers View complete reference list from CitEc
Citations: View citations in EconPapers (1)

Downloads: (external link)
http://www.sciencedirect.com/science/article/pii/S0960148119313187
Full text for ScienceDirect subscribers only

Related works:
This item may be available elsewhere in EconPapers: Search for items with the same title.

Export reference: BibTeX RIS (EndNote, ProCite, RefMan) HTML/Text

Persistent link: https://EconPapers.repec.org/RePEc:eee:renene:v:147:y:2020:i:p1:p:69-76

DOI: 10.1016/j.renene.2019.08.131

Access Statistics for this article

Renewable Energy is currently edited by Soteris A. Kalogirou and Paul Christodoulides

More articles in Renewable Energy from Elsevier
Bibliographic data for series maintained by Catherine Liu ().