Alkali metal bifunctional catalyst-sorbents enabled biomass pyrolysis for enhanced hydrogen production

Ming Zhao, Muhammad Zaki Memon, Guozhao Ji, Xiaoxiao Yang, Arun K. Vuppaladadiyam, Yinqiang Song, Abdul Raheem, Jinhui Li, Wei Wang and Hui Zhou

Renewable Energy, 2020, vol. 148, issue C, 168-175

Abstract: Alkali ceramics are well-known high temperature CO2 sorbents in forms of zirconates or orthosilicates with catalytic tar cracking ability prior to or after carbonation. In this study, Li2ZrO3, Li4SiO4, and Na2ZrO3 were selected as catalyst-sorbent bifunctional materials to enhance the pyrolysis of sawdust. This study investigated the synergy between the alkali metal bifunctional materials under pyrolytic conditions. The weight loss data and gas yield trends in the temperature between 200 and 800 °C demonstrated a combined catalytic process and gas-solid reaction. A metal carbonate phase was formed after the reaction of capturing CO2. The CO2 capture promoted H2 production because of Le Chatelier principle and the formation of carbonate phase assisted tar cracking reactions. H2 production increased from 5.73 mmol g−1 to 8.87 mmol g−1, 15.85 mmol g−1, and 13.67 mmol g−1 in the presence of Li2ZrO3, Li4SiO4, and Na2ZrO3, respectively. At temperatures around 700 °C, CO was released due to secondary cracking reaction and the Boudouard reaction of CO2 released from the sorbents. Overall, the alkali ceramics present the catalyst-sorbent bifunctional activity for enhancing H2 production during biomass pyrolysis.

Keywords: Alkali ceramics; Bifunctional catalyst-sorbent; Biomass pyrolysis; Hydrogen production; Char gasification (search for similar items in EconPapers)
Date: 2020
References: View references in EconPapers View complete reference list from CitEc
Citations: View citations in EconPapers (3)

Downloads: (external link)
http://www.sciencedirect.com/science/article/pii/S0960148119318762
Full text for ScienceDirect subscribers only

Related works:
This item may be available elsewhere in EconPapers: Search for items with the same title.

Export reference: BibTeX RIS (EndNote, ProCite, RefMan) HTML/Text

Persistent link: https://EconPapers.repec.org/RePEc:eee:renene:v:148:y:2020:i:c:p:168-175

DOI: 10.1016/j.renene.2019.12.006

Access Statistics for this article

Renewable Energy is currently edited by Soteris A. Kalogirou and Paul Christodoulides

More articles in Renewable Energy from Elsevier
Bibliographic data for series maintained by Catherine Liu ().